4. “The Birthday” — Season 3, Episode 1

Before there was Klaus, there was Tyler – Caroline’s hunky hybrid boyfriend. Their flirtatious tension reached a boiling point, and when they shared a steamy kiss at Elena’s birthday party, clothes flew off faster than you could say “supernatural libido.” The CW knows how to turn up the heat, and this scene was no exception.

5. “500 Years Of Solitude” — Season 5, Episode 11

Caroline and Klaus were like oil and water, constantly at odds. But underneath all that animosity, there was an undeniable attraction. When they finally let go of their inhibitions and got frisky in the woods, it was nothing short of explosive. A love-hate relationship never looked so good.

6. “The Turning Point” — Season 1, Episode 10

Elena and Stefan’s first-time rendezvous set our screens ablaze. Their love may have been forbidden, but that didn’t stop them from indulging in some sizzling vampire-human action. It was a turning point for their relationship, and let’s just say it wasn’t just the temperature that was rising. Stelena fans, prepare to swoon!